Industrial Catalysis 1995 Vol.3

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Application of Rare-earth Containing Catalysts in Fertiliser Industry
Sun Jinyi
  
Abstract779)      PDF(pc) (291KB)(1137)       Save
The research in and application of rare-earth containing catalysts for fertiliser industry were outlined,especially the performance of domestic rare-earth containing catalysts as well as the functioning mechanisms of rare earth in them. Research in the aspect both at home and abroad was also briefly described.
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Preparation, Performance and Industrial Application of Ziegler-Natta Type Homogeneous Hydrogenation Catalyst
Tang Zhanzhong
  
Abstract857)      PDF(pc) (118KB)(1139)       Save
This paper briefly reviews the compositions and preparation methods of Ziegler-Natta type homogeneous hydrogenation catalyst.The performance and industrial application of the catalyst are also outlined.
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1,4-Butynediol Synthesis and Its Catalysts
Gong Churu; Li Xiaolin; Yang Hongchun
  
Abstract873)      PDF(pc) (155KB)(1234)       Save
This article reviews the technical routes for the manufacture of 1,4-butynediol and the catalysts so far reported both at home and abroad. The process and catalyst provided by Godognola greatly improves the production rate and selectivity.
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Development of DG Type Carbon Monoxide HTS Catalyst with Low Density and High Strength
Li Jiemin; Ma Baoxia
  
Abstract894)      PDF(pc) (369KB)(1095)       Save
Development of a CO high temperature shift catalyst,suited for large ammonia plant, was described. The catalyst has density as low as 1.25 kg·L-1, side strength(in reduced state) higher than 350 N·cm-1,bulk sulfur content lower than 500 ppm(wt) and high activity in lower temperature range. Main features of its manufacture technology and result of industrial test run are also summerized.
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Influence of Alumina Addition on the Performance of Carbon Monoxide HTS Catalyst
Cui Fang; Li Jide
  
Abstract829)      PDF(pc) (110KB)(1098)       Save
The influence of alumina addition on the bulk density, mechanical strength,activity and thermal stability of high temperature shift(HTS) catalyst was studied in laboratory. The study showed that addition of appropriate amount of alumina may remarkably improve the performance of Fe-Cr HTS catalyst.
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New Spraying Process for Manufacture of Spherical Ammonia Synthesis Catalyst
Liu Huazhang; Hu Zhangneng; Jiang Zurong; Li Yanying; Sun Tujin
  
Abstract886)      PDF(pc) (178KB)(1004)       Save
A new method for manufacture of spherical ammonia synthesis catalyst was described in this paper. The experimental results demonstrated that the spherical catalyst manufactured by the spraying process with fixed and rotational sprayer resulted particularly high granulated efficiency with the sphericized co-efficient near to 1,high machanical strength,low cost and operation safety.
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Influence of Synthesis Conditions of Rare Earth Heteroatomic Zeolites on Toluene Alkylation Reaction
Wang Xiaohan, Chen Lianzhang
  
Abstract795)      PDF(pc) (176KB)(966)       Save
[La]-AlZSM-5 zeolites were synthesized using lanthanum nitrate, sodium silicate and acidic aluminium sulfate as raw materials and n-butyl amine as templating agent.XRD and cell dimensions measurement showed that La atoms had entered zeolite skeleton and partly substituted Al atoms.The paper discussed the influence of different synthesis conditions on toluene alkylation reaction. Experimental results showed that the [La]-AlZSM-5 zeolites synthesized under lower alkality,crystallation time of 80 hours and with templating agent C4H11N/SIO2=0.045 exhibited high activity and selectivity on toluene alkylation reaction. Tolune alkylation reactions carried out over the zeolite catalysts resulted maximum PMEB selectivity of 94.81% and toluene conversion of 22.07%.
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Study on Cu/SiO2 Catalyst Prepared By Ion Exchange Method for the Dehydrogenation of Methanol to Methyl Formate
Li Gong1; Zhang Hongsheng2; Xie Guangen2
  
Abstract767)      PDF(pc) (142KB)(967)       Save
Cu/SiO2 catalyst prepared by ion exchange method, compared with that from impregnation,shows higher stability for the dehydrogenation of methanol to methyl formate,with larger surface area of Cu,higher dispersity and smaller crystallines,which means that Cu crystallines on the support will not be easily aggregated during the reaction.
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are Earth Recovery from Filter Liquor of Molecular Seive Manufacture by Extraction

Zhang Jiguang
  
Abstract719)      PDF(pc) (217KB)(1058)       Save
A process for recovery of rare earth from filter liquor of molecular seive manufacture by extraction was described,including laboratory experimental,pilot test results and Industrial performance.Comared with existing ammonia liquor route, the extraction process gives higher recovery, better product quality, less pollution and lower operating cost.
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Performance of T306 Type Desulfurizer in the Modification of a Desulfurization Process
Cao Bin
  
Abstract775)      PDF(pc) (105KB)(988)       Save
The performance of a ZnO-type high efficiency desulfurizer in the modification of a feedstock oil desulfurization process in a ammonia plant was assessed in this article.Satisfactory strength,sulfur capacity and desulfurization level were shown by the desulfurizer in industrial operation.
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Study on the Sulfiding of Co-Mo-K/Al2O3 Water Gas Shift Catalyst
Shen Yong; Zhu Tiancun; Lu Xiongzhang
  
Abstract830)      PDF(pc) (243KB)(1044)       Save
The dry semiwater gas with addition of carbon disulfide, which is practically used in industry,was used as gas supply for sulfiding experiments. By means of TG,DTA,SEM+WDX,SEM+EDX and XRD techniques,isothermal and temperature programmed sulfiding experiments of sulfur resistant shift catalyst Co-Mo-K/Al2O3,its different components and their combinations (γ-Al2O3,MoO3, Co3O4, MoO3/Al2O3, CoO/Al2O3, K2CO3/Al2O3, Co-Mo/Al2O3, Co-K/Al2O3 and Mo-K/Al2O3) were carried out. Effect of temperature on the sulfiding processs were investigated. Sulfiding performance of different components were compared. The roles of different components in the sulfiding processs were discussed.
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Status of Catalysts Used in Domestic Large-Scale Ammonia Plants
Ding Jiahao
  
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Computer-aided Tracing and Forecasting of the Performance of CO HTS Catalyst
Xu Bo
  
Abstract763)      PDF(pc) (126KB)(1084)       Save
The performance of CO high temperature shift catalyst on a fertilizer plant of Anqing Petrochemical Works was traced with the help of computer in its whole service life and various schemes for changeover of the catalyst evaluated by computer-assisted forecasting.Practical operation of the catalyst was in good accordance with the forecast.
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